ISSN:
0044-2313
Keywords:
Ruthenium
;
boranes
;
organoruthenaboranes
;
preparation
;
mass, n.m.r. spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organoruthenaboran-Chemie. IX. Die Reaktion von [{(η6-C6Me6)RuCl2}2] und [{(η6-MeC6H4-4-iPr)RuCl2}2] mit dem [nido-B9H12]--AnionDie Reaktion zwischen [NnBu4][nido-B9H12] und [{(η6-C6Me6)RuCl2}2] in CH2Cl2-Lösung ergibt [5-Cl-6-(η6-C6Me6)-nido-6-RuB9H12] (12%), [6-(η6-C6Me6)-nido-6-RuB9H13] (1%) und [1-(η6-C6Me6)-isocloso-1-RuB9H9] (2%). Die entsprechende Reaktion mit dem p-Cymol-Analogon [{(η6-MeC6H4-iPr)RuCl2}2] ergibt [5-Cl-6-(η6-MeC6H4-4-iPr)-nido-6-RuB9H12] (15%), [6-(η6-MeC6H4-4-iPr)-nido-6-RuB9H13] (1%) und [1-(η6-MeC6H4-4-iPr)-isocloso-1-RuB9H9] (3%). Die Produkte sind gelbe, luftstabile Festkörper; sie wurden chromatographisch getrennt und massenspektroskopisch und NMR-spektroskopisch charakterisiert.
Notes:
Reaction between [NnBu4][nido-B9H12] and [{(η6-C6Me6)RuCl2}2] in CH2Cl2 solution yields [5-Cl-6-(η6-C6Me6)-nido-6-RuB9H12] (12%), [6-(η6-C6Me6)-nido-6-RuB9H13] (1%), and [1-(η6-C6Me6)-isocloso-1-RuB9H9] (2%). The corresponding reaction with the p-cymene analogue [{(η6-MeC6H4-4-iPr)RuCl2}2] yields [5-Cl-6-(η6-MeC6H4-4-iPr)-nido-6-RuB9H12] (15%), [6-(η6-MeC6H4-4-iPr)-nido-6-RuB9H13] (1%), and [1-(η6-MeC6H4-4-iPr)-isocloso-1-RuB9H9] (3%). The products were all yellow, air-stable solids; they were separated by chromatography and characterized by mass spectrometry and n.m.r. spectroscopy.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19915980105
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