ISSN:
1040-0397
Keywords:
SDS/dodecane/l-pentanol/0.1 M NaClaq anionic oil-in-water microemulsion
;
Structure determination
;
Electrochemical methods
;
Ferrocene
;
Fe(CN)63-
;
Methyl viologen
;
Apparent diffusion coefficients
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The relationship between apparent diffusion coefficients, D′, of electroactive probe and thc microstructure of an oil-in-water anionic microemulsion, sodium dodecyl sulfate (SDS)/dodecane/I-pentanol/0.1M NaCIaq has been investigated. Three probes, ferrocene (Fc), Fe(CN)63- and methyl viologen (MV2+) allowed the effect of ditrerent microstructure and interactions on the D′-values to be investigated. The results indicate that the droplet as well as hicontinuous microemulsion structures can be identified and point to the effects of cross- phase exchange, partitioning, and multiple binding on the D′-values.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/elan.1140080810
Permalink
