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Conjugated Additions in Hydrogen Fluoride (1969)

German, L. S. ; Knunyantz, I. L.

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 8 (1969), S. 349-356

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ISSN: 0570-0833

Keywords: Hydrogen fluoride ; Solvents ; Fluorination ; Fluorine ; Addition ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Fluorine and another substituent can be added in a single step to compounds having CC double bonds in anhydrous hydrogen fluoride. It is possible in this way to obtain e.g. α-fluorinated β-halogeno, β-alkyl, β-nitro, and β-amino compounds, and also (in some cases by secondary reactions) fluorinated ethers, alcohols, esters, and carboxylic acids, β-fluoro alcohols can be obtained by conjugated “hypofluorination” in the presence of oxenium ions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.196903491

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