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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 61 (1990), S. 187-201 
    ISSN: 1572-9613
    Keywords: Spherical model ; dipolar systems ; dielectric constant ; dipolar system simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A mean spherical model of classical dipoles on a simple cubic lattice of sideM=2N+1 sites is considered. Exact results are obtained for finite systems using periodic boundary conditions with an external dielectric constantɛ′ and using reaction field boundary conditions with a cutoff radiusR c ⩽N and an external dielectric constantɛ′. The dielectric constant in the disordered phase is calculated using a variety of fluctuation formulas commonly implemented in Monte Carlo and molecular dynamics simulations of dipolar systems. The coupling in the system is measured by the parametery=4πμ 2/9kT, whereμ 2 is the fixed mean square value of the dipole moments on the lattice. The system undergoes a phase transition aty≈2.8, so that very high dielectric constants cannot be obtained in the disordered phase. The results show clearly the effects of system size, cutoff radius, external dielectric constant, and different measuring techniques on a dielectric constant estimate. It is concluded that with periodic boundary conditions, the rate of approach of the dielectric constant estimate to its thermodynamic limit is asN −2/3 and depends only weakly onɛ′. Methods of implementing reaction field boundary conditions to give rapid convergence to the thermodynamic limit are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 50 (1988), S. 813-838 
    ISSN: 1572-9613
    Keywords: Spherical model ; Coulombic systems ; correlation function decay ; Stillinger-Lovett relations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We consider simple cubic lattice systemsΛ ind dimensions with a continuous real charge variableq(n) at each lattice siten. These variables are subject t'o a mean spherical constraint forcing 〈∑n∈Λ q 2(n)〉=‖Λ‖Q 2, where ‖Λ‖ is the number of lattice sites inΛ andQ is an elementary charge. The energy of the charges comes from interactions with an electrostatic potential, which is the solution of a symmetric second-difference Poisson equation on the lattice. Two cases are considered, both of which allow the inclusion of the effects of a fixed, constant, external electric field. On the latticeΛ 1=[1,N]⊗d , a Neumann condition is imposed at the surface of the lattice. The latticeΛ 2=[1,N]⊗ [−M,M]⊗(d−1) is periodic in each direction ranging over [−M, M] and has a Dirichlet condition imposed at the other two surfaces. OnΛ 2 a finite electric field may be applied, while onΛ 2 a finite potential difference may be applied across the lattice. The models are exactly solvable. We study the distribution functions on each system and show that they satisfy appropriate forms of the first two Stillinger-Lovett moment conditions. The two charge distribution functions show screening behavior at high temperature and extreme short range at an intermediate temperatureT 0(d), and oscillate as they decay to zero forT〈T 0(d). Because of the continuous nature of the charge variables, there is no Kosterlitz-Thouless transition in two dimensions. In three dimensions the change in the decay behavior of the distribution functions atT〈T 0(d) is precursor to a phase transition to a charge ordered state.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 55 (1989), S. 127-139 
    ISSN: 1572-9613
    Keywords: Spherical model ; Coulombic systems ; correlation function decay ; surface properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Studies of the mean spherical model with Coulomb interactions are continued, by considering a system on ad-dimensional lattice which is periodic ind−1 dimensions and has a free surface in the remaining dimension. It is shown explicitly that correlations along the free surface decay asy −d ind dimensions and show that the surface properties of this model are those expected for a charged system in its plasma phase.
    Type of Medium: Electronic Resource
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