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  • PACS. 75.50.Lk Spin glasses and other random magnets – 75.10.Nr Spin-glass and other random models  (1)
  • Spiral growth  (1)
  • 1
    ISSN: 1434-0879
    Keywords: Key words Calcium oxalate monohydrate ; Glycosaminoglycans ; Atomic force microscopy ; Inhibition mechanisms ; Two-dimensional nucleation ; Spiral growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Atomic force microscopy (AFM) was applied to the (-101) faces of calcium oxalate monohydrate (COM) crystals grown from calcium oxalate (CaOx) solutions. Microstructures of many spiral hillocks with step height of 1 nm were observed on the faces. Then using AFM in situ, we analysed the re-growth process of the spiral steps on the face of COM seed-crystals in CaOx growth solutions that contained growth inhibitors of glycosaminoglycans and studied their inhibition mechanisms on COM crystals. The total morphology of the faces of COM seed crystals re-grown in the CaOx growth solutions was assessed by scanning electron microscopy (SEM). In the growth solution without glycosaminoglycans (control experiment) or with chon-droitin sulphate (ChS), AFM images and SEM micrographs of the faces of the re-grown seed crystals showed two-dimensional (2D) nucleation although 2D nucleation was delayed in the presence of ChS. However, the addition of dermatan sulphate (DS) to the growth solution resulted in isotropic growth by a step flow mode and spiral mechanism. With regard to the main inhibition mechanisms of two glycosaminoglycans (ChS and DS) on COM crystals, it can be concluded from these results that ChS delays 2D nucleation and DS inhibits 2D nucleation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 22 (2001), S. 203-211 
    ISSN: 1434-6036
    Keywords: PACS. 75.50.Lk Spin glasses and other random magnets – 75.10.Nr Spin-glass and other random models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: Aging in spin glasses (and in some other systems) reveals astonishing effects of `rejuvenation and memory' upon temperature changes. In this paper, we propose microscopic mechanisms (at the scale of spin-spin interactions) which can be at the origin of such phenomena. Firstly, we recall that, in a frustrated system, the effective average interaction between two spins may take different values (possibly with opposite signs) at different temperatures. We give simple examples of such situations, which we compute exactly. Such mechanisms can explain why new ordering processes (rejuvenation) seem to take place in spin glasses when the temperature is lowered. Secondly, we emphasize the fact that inhomogeneous interactions do naturally lead to a wide distribution of relaxation times for thermally activated flips. `Memory spots' spontaneously appear, in the sense that the flipping time of some spin clusters becomes extremely long when the temperature is decreased. Such memory spots are capable of keeping the memory of previous ordering at a higher temperature while new ordering processes occur at a lower temperature. After a qualitative discussion of these mechanisms, we show in the numerical simulation of a simplified example that this may indeed work. Our conclusion is that certain chaos-like phenomena may show up spontaneously in any frustrated and inhomogeneous magnetic system, without impeding the occurrence of memory effects.
    Type of Medium: Electronic Resource
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