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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 77 (1984), S. 87-95 
    ISSN: 1573-5036
    Keywords: Ammophila arenaria ; Coastal environments ; Hippophaë rhamnoides ; Soil acidification ; Soil microorganisms ; Sulphur oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary S-oxidation was studied in samples of (a) coastal sands lacking vegetation; (b) sands from beneath isolated stands ofAmmophila arenaria andHippophaë rhamnoides; and (c) dune soils obtained from beneath vegetation growing on mature dunes. S-oxidation in samples taken from dune environments was compared with the process in a fertile garden soil. Elemental-S was oxidized to SO 4 2− in all samples, with S2O 3 2− being formed as intermediates. S-oxidation was most pronounced in the dune soil, followed by the garden soil,Ammophila arenaria andH. rhamnoides rhizospheres and finally the non-vegetated sand. The rate of S-oxidation thus generally increased with increasing C and N content, increasing vegetation cover and decreasing soil-sand pH. Maximum S-oxidation occurred at 30–37°C, but some of the intermediates appeared even at 45°C, presumably indicating abiotic S-oxidation at high temperatures. S-oxidation decreased the pH of the two soils studied, but did not markedly acidify the unvegetated or rhizosphere sands.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: Nitrification ; Organic matter ; Sulphur cycle ; Sulphur oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effects of wheat straw and pressed sugar beet pulp on sulphur oxidation were determined in a loam soil amended with 1% (w/w) elemental sulphur. Wheat straw stimulated the oxidation of elemental sulphur over the first 2 to 3 weeks of the incubation period, resulting in an increase in LiCl-extractable sulphate. After 4 to 7 weeks incubation however, the only significant increase in soil sulphate followed the 1% straw addition, while at week 7 sulphate concentrations in the 0.25% and 5.0% straw amended soils were lower than the control. Pressed sugar beet pulp (1% w/w) initially stimulated the oxidation of elemental sulphur in the soil, but by weeks 3 to 7 of the incubation period rates of oxidation in pulp-amended soils were lower than the control. Towards the end of the incubation period however, sulphate concentrations in the amended soils exceeded the control values, significantly so by week 11. The concentration of thiosulphate and tetrathionate also increased in soils receiving sugar beet pulp. Nitrification was inhibited in soils in which sulphur oxidation was actively occurring. Although possible alternatives are mentioned, such inhibition appears to result from a decrease in soil pH brought about by the oxidation of elemental sulphur to sulphuric acid.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 12 (1979), S. 709-712 
    ISSN: 1612-1112
    Keywords: Acrylamide synthesis ; High-performance liquid chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Two liquid chromatographic methods are described for the separation and determination of components in the production of acrylamide by the catalytic hydration of acrylonitrile. The first of these provides a rapid technique by which concentrations and conversion can be directly determined for process control applications, whilst the second represents a more rigorous separation of all possible impurities for quality control purposes.
    Type of Medium: Electronic Resource
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