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The classification of tensor surface harmonic functions for clusters and coordination compounds (1989)

Johnston, Roy L. ; Mingos, D. Michael P.

Springer

Theoretical chemistry accounts 75 (1989), S. 11-32

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ISSN: 1432-2234

Keywords: Tensor surface harmonics ; Clusters ; Polyhedral topology ; Classification

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract A simple method for enumerating theL σ and $$L^\pi /\bar L^\pi $$ functions for polyhedral cluster and coordination molecules, within Stone's tensor surface harmonic methodology, is described. The nature of theL σ orbitals which are generated depends on the polyhedral topology and in particular the number of layers of vertices and the number of vertices within each layer. The $$L^\pi /\bar L^\pi $$ functions are enumerated from theL σ's by a number of spherical harmonic multiplication rules.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01151230

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