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  • 1
    Electronic Resource
    Electronic Resource
    Octacarbonylbis {μ-(tris(trimethylsilyl)methyl]indany l} dimanganese with Two Monoalkyl Indium Groups Bridging the Mn-Mn Bond (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 1137-1139 
    Details
    ISSN: 0009-2940
    Keywords: Tetraindane(4) ; Indium(I) ; Mn-Mn bond ; Indium alkyl bridge ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrahedra-tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) (1) reacts with decacarbonyldimanganese(0) to yield the bright red crystalline title compound 2, in which two carbonyl ligands are replaced by two InR fragments. The crystal structure determination of 2 shows two Mn(CO)4 groups (Mn-Mn 313.7 pm) bridged by two monoalkylindium units and a planar Mn2In2 molecular center.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951281114
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Reaction of the Alkylindium(I) Compound In4[C(SiMe3)3]4 with Octacarbonyldicobalt: Bridging of the Co—Co Bond by one or two In—C(SiMe3)3 GroupsDedicated to Prof. Dr. Kurt Dehnicke on the occasion of his 65th birthday. (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 397-400 
    Details
    ISSN: 0009-2940
    Keywords: Tetraindane(4) ; Indium(I) ; Co—Co bond ; Indium alkyl bridge ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: tetrahedra-Tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) (1) reacts with octacarbonyldicobalt to yield two products, depending on the stoichiometric ratio of the starting compounds: By replacement of one bridging carbonyl group a dicobalt monoindium derivative 2 is formed, which contains a Co—Co bond [256.81(5) pm] bridged by one carbonyl and one monoalkylindium group. While 2 is a monomer in benzene solutions, it dimerizes in the solid state by an interaction of the oxygen atom of the bridging carbonyl group to the coordinatively unsaturated In atom of a second molecule across a center of symmetry. Another compound (3) is formed by the replacement of both bridging carbonyl ligands, which exhibits a strongly distorted Co2In2 tetrahedron with normal Co—In bond lengths of 253.44(6) pm, but long Co—Co [280.14(6) pm] and In—In distances [336.18(6) pm].
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19961290406
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  • 3
    Electronic Resource
    Electronic Resource
    Die Kristallstruktur eines bisaxial mit tert-Butylacetylen substituierter GermaniumhemiporphyrazinsHerrn Professor Harry Hahn zum 65. Geburtstag gewidmet. (1980)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1980 (1980), S. 1946-1951 
    Details
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of a Bisaxial with tert-Butylacetylene Substituted Germanium Hemiporphyracinetrans-Bis(3,3-dimethyl-1-butyneyl) hemiporphyracine germanium crystallizes by sublimin furane in triclinic crystals with the space group P1 and the lattice constants a = 860.4, b = 960.7, c = 1141.6 pm; α = 74.01, β = 113.62, γ = 108.50°. The unit cell contains one centrosymmetric molecule, in which the germanium atom is surrounded in a distorted octahedral coordination by four nitrogen atoms of the hemiporphyracine ligand (Ge - N: 195.6 and 217.2 pm) and two carbon atoms of the tert-butylacetylene group (Ge - C: 193.8 pm). The germanium hemiporphyracine moiety is mostly planar.
    Notes: trans-Bis(3,3-dimethyl-1-butinyl)hemiporphyrazin-germanium kristallisiert beim Sublimieren in triklinen Kristallen, mit der Raumgruppe P1 und den Gitterkonstanten a = 860.4, b = 960.7, c = 1141.6 pm; α = 74.01, β = 113.62, γ = 108.50°. Die Elementarzelle enthält ein zentrosymmetrisches Molekül, in dem das Germaniumatom verzerrt oktaedrisch von 4 Stickstoffatomen des Hemiporphyrazinliganden (Ge - N: 195.6 und 217.2 pm) und 2 Kohlenstoffatomen der tert-Butylacetylengruppen (Ge - C: 193.8 pm) umgeben ist. Der Germaniumhemiporphyrazin-Teil ist weitgehend eben gebaut.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.198019801204
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  • 4
    Electronic Resource
    Electronic Resource
    Synthese und Struktur von Cyano(dihydrodibenzo[b,i]-[1,4,8,11]tetraazacyclotetradecinato)cobalt(III) (1984)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1984 (1984), S. 1791-1797 
    Details
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Cyano(dihydrodibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)-cobalt(III)Cyano(dihydrodibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)cobalt(III) (CotaaCN) is formed by reaction of Cotaa with sodium cyanide and oxygen. CotaaCN crystallizes orthorhombic, space group P212121 with the cell dimensions a = 698.6 pm, b = 1466.2 pm, and c = 1553.7 pm, Z = 4. The compound is a pentacoordinated monomer with a Co—C distance of 182 pm. The IR spectrum of this monomeric compound exhibits a CN-valence frequency at 2116 cm-1.
    Notes: Cyano(dihydrodibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)cobalt(III) (CotaaCN) wird durch Umsetzung von Cotaa mit NaCN und Sauerstoff dargestellt. CotaaCN kristallisiert orthorhombisch in der Raumgruppe P212121 mit den Gitterkonstanten a = 698.6 pm, b = 1466.2 pm und c = 1553.7 pm, Z = 4. Die Verbindung liegt als pentakoordiniertes Monomer vor. Der Co—C-Abstand beträgt 182 pm. Die CN-Valenzschwingung im IR-Spektrum dieser monomeren Verbindung liegt bei 2116 cm-1.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.198419841105
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