ISSN:
1434-1948
Keywords:
Tetrathionates
;
Pentathionates
;
Sulfato ligands
;
Cobalt(III) complexes
;
Thiobacillus ferrooxidans
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
K[Co(tren)(NH3)(SO4)](S4O6)·2(H2O) (1) and [cis-α-Co-(trien)(NH3)Cl](S5O6) (2) have been prepared unexpectedly while attempting to obtain crystals suitable for X-ray diffraction of [Co(tren)(NH3)Cl](S4O6) (3) and of [cis-Co(trien)(NH3)Cl](S4O6) (4), respectively. 1 is derived from 3 by hydrolysis of the tetrathionate anion resulting in a sulfato moiety which displaces the chloro ligand from the coordination sphere of the metal center. 2 is derived from 4 by hydrolysis of the tetrathionate anion followed by reformation into pentathionate anion and H2S, as described in previous chromatographic work by Steudel. Compounds 1 and 2 have been characterized by elemental analyses and by single-crystal X-ray diffraction studies.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
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