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(Diphenylphosphanyl)(tetramethylcyclopentadienyl)thallium(I) (1993)

Schumann, Herbert ; Ghodsi, Tahereh ; Esser, Lothar ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 126 (1993), S. 591-594

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Details

ISSN: 0009-2940

Keywords: Indium(I) complexes ; Thallium(I) complexes ; Cyclopentadiene, (diphenylphosphanyl)tetramethyl- ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: (Diphenylphosphanyl)(tetramethylcyclopentadienyl)thallium(I)(Diphenylphosphanyl)tetramethylcyclopentadiene (1) reacts with TlOC2H5 to form Tl[C5Me4PPh2] (2). In a transmetallation reaction 2 reacts with InCl to yield the corresponding In[C5Me4PPh2] complex (3). The 1H-, 13C-NMR-and mass spectra as well as the single-crystal X-ray structure analysis of the monomeric 2 are reported and discussed.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19931260307

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