ISSN:
1572-8927
Keywords:
Tri-n-dodecylammonium chloride and nitrate
;
aggregation equilibria
;
mixed species formation equilibria
;
toluene
;
vapor pressure osmometry
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The aggregation and mixed species formation equilibria of tri-n-dodecylammonium chloride (TLAHCl) and tri-n-dodecylammonium nitrate (TLAHNO3) dissolved in toluene have been studied by vapor pressure osmometry at 40°C. The experimental data can be best fit by the formation of the aggregates (TLAHCl)2 (log β2,0 = 1.35±0.06), (TLAHNO3)2 (log β2,0 = 1.75±0.20), (TLAHNO3)3 (log β0,3 = 3.6±0.1), and the mixed species (TLAHCl)(TLAHNO3)2 (log β1,2 = 3.3±0.2).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00972926
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