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Trimethylphosphane Complexes of Nickel, Cobalt, and Iron - Model Compounds for Homogeneous Catalysis (1980)

Klein, Hans-Friedrich

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 19 (1980), S. 362-375

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Details

ISSN: 0570-0833

Schlagwort(e): Trimethylphosphane complexes ; Phosphane ligands ; Homogeneous catalysis ; Catalysis ; Cobalt ; Nickel ; Iron ; P ligands ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: One of the greatest achievements of organometallic chemistry in the last ten years has been the experimental proof that transition metal-to-carbon bonds are thermodynamically about as stable as those between main group elements and carbon. The present contribution demonstrates how simply constituted alkylnickel, -cobalt, and -iron complexes are obtained by means of a kinetic stabilization using suitable neutral ligands and what information these model compounds can provide with respect to the course of processes in homogeneous catalyses.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/anie.198003621

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