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A theoretical study of the rotational distribution of no resulting from dissociation of HNO (1998)

Cobos, C. J.

Springer

Reaction kinetics and catalysis letters 64 (1998), S. 199-205

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ISSN: 1588-2837

Keywords: Unimolecular reactions ; NO rotational distribution ; HNO radical

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Nascent NO (X2ΠΩ=1/2, 3/2, v=0) rotational distributions following the unimolecular dissociation of HNO at 5 and 300 K have been calculated at excess energies from 5 to 500 cm−1, using the statistical adiabatic channel model on anab initio potential energy surface. The influence of the tunneling effect through the adiabatic channel barriers on the average rotational energies is investigated.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02475389

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