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  • 1
    Electronic Resource
    Electronic Resource
    Surface and subsurface products of the interaction of O2 with Ag under catalytic conditions (1991)
    Springer
    Catalysis letters 11 (1991), S. 253-265 
    Details
    ISSN: 1572-879X
    Keywords: Silver ; oxygen ; selective oxidation ; thermal desorption ; subsurface compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Polycrystalline Ag treated with O2 at pressures up to 1 bar and at temperatures up to 920 K was examined by TDS. It was found that the peak commonly observed at 595±25 K and assigned to adsorbed atomic oxygen (Oa) is shifted to higher desorption temperatures with rising dosing temperatures. Since saturation of the uptake was not possible either, this peak was identified as dissolved atomic oxygen (Od). The existence of a maximum for the O2 uptake after exposure at 820 K was found. Hence, under conditions of formaldehyde synthesis (≈ 920 K) the ability of the catalyst to dissolve oxygen is near its maximum.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00764316
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Microstructure of the activated industrial ammonia synthesis catalyst (1991)
    Springer
    Catalysis letters 11 (1991), S. 19-31 
    Details
    ISSN: 1572-879X
    Keywords: Ammonia synthesis ; iron catalyst ; surface characterization ; promoter effects ; nitrides ; ion scattering spectroscopy ; XPS ; HRTEM
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Industrial doubly-promoted iron catalysts and model systems of singly-promoted K- and Al-iron catalysts were characterised by their catalytic performance at 1 bar pressure. The relevance of bulk nitrogen for catalytic performance is shown. The catalysts were also activated in an in-situ reaction chamber of a He-ion scattering spectrometer (ISS) and their top atomic layer elemental composition was determined after they had reached similar performance as in the microreactor tests. The bulk microstructure of these samples was investigated by high resolution transmission electron microscopy (TEM) and microdiffraction. All evidence indicates that small highly crystalline α-Fe platelets act as active phase. Their surfaces are covered to a large extent by promotor compounds which are partly present as poorly crystalline aggregates with iron oxide leaving only a small fraction of elemental iron directly exposed to the gas phase. The intimate contact between iron crystals and promoters particles prevents recrystallisation and is the key to the understanding of the structural stability of the catalyst system.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00866897
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Ruthenium supported on zeolite A: preparation and characterisation of a stable catalyst for ammonia synthesis (1994)
    Springer
    Catalysis letters 25 (1994), S. 61-74 
    Details
    ISSN: 1572-879X
    Keywords: Ammonia synthesis ; supported ruthenium catalyst ; dispersed ruthenium ; instationary kinetics ; lifetime effects ; ruthenium oxidation ; surface analysis ; XPS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Reaction of Ru(NH3)6Cl3 with Na-A and K-A zeolites yielded oligomeric amino-oxo-complexes supported on the zeolite. Controlled thermal activation under hydrogen converted the precursor in a two-step reaction into an active catalyst with good long-term stability and resistance against small doses of oxygen poison. Several nanometers sized Ru metal particles are chemically bonded to the zeolite surface which provides in the K form an alkali promoter at the metal-zeolite interface. Extensive oxidation breaks the metal-support anchoring and re-reduction produces Ru metal particles sintering rapidly into large metal crystals with only small residual catalytic activity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00815416
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
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