ISSN:
1434-1948
Keywords:
Alkylamines
;
Arylamines
;
Zinc
;
Cadmium
;
Mercury
;
X-ray diffraction
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Homoleptic intramolecularly stabilized organozinc, -cadmium, and -mercury compounds MR2, with R bearing an amino function, have been synthesized from the corresponding metal dichlorides MCl2 and the lithium salts LiC6H4CH2NEt2-2 (1), LiC6H3(CH2NMe2)2-2,6 (2), LiC6H3(CH2NEt2)2-2,6 (3), (LiCH2CH2CH2)2NMe (4), and LiCH2CH2CH2NC5H10 (5). The crystal structures of Hg(C6H4CH2NEt2-2)2 (1c), [M(CH2CH2CH2)2NMe]2 [M = Zn (4a), Hg (4c)], and of M(CH2CH2CH2NC5H10)2 [M = Zn (5a), Cd (5b)] have been determined by X-ray diffraction. 4a and 4c form dimers with an unusual coordination number (three) of the central metal.
Type of Medium:
Electronic Resource
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