ISSN:
1572-879X
Keywords:
magnesium molybdates
;
oxidative dehydrogenation of propane
;
acidic properties
;
lattice oxide ions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Catalytic activities of magnesium molybdates were investigated for the oxidative dehydrogenation of propane with and without molecular oxygen under atmospheric pressure. Catalytic properties drastically changed with the catalyst composition, and it turned out that Mg0.95MoOx catalysts having slight excess molybdenum showed the highest activity in the oxidative dehydrogenation of propane, which gave 61% selectivity to propene at 22% conversion of propane at 515°C. The catalytic activities strongly depended on the acidic properties of the catalysts. It was also revealed that the lattice oxide ions of the catalysts participated as an active oxygen in the oxidative dehydrogenation of propane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00807004
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