ISSN:
0887-624X
Keywords:
palladium catalyst
;
allene derivatives
;
nucleophile bearing aryl halides moieties
;
multibranched polymer
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A novel polymerization method of allene derivatives with nucleophiles bearing aryl halide moieties (A-B type) is described. By the polymerization of hexylallene with malonates bearing an aryl iodide part, polymers consisting both of internal and exomethylene (exo) double bonds were obtained by mean of the coupling reaction of three different components in high yields. On the other hand, a polymer obtained from phenylallene was selectively composed of internal double bonds (E and Z). By the reaction of hexylallene with a malonate bearing two aryl halide moieties (A-B2 type), a multibranched polymer was also obtained. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2097-2103, 1997
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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