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Aluminum-27 NMR study of some AlCl3−MCl molten systems (1986)

Taulelle, Francis ; Popov, Alexander I.

Springer

Journal of solution chemistry 15 (1986), S. 463-471

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ISSN: 1572-8927

Keywords: AlCl3−MCl molten salts ; aluminum-27 NMR ; Dispa technique

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Aluminum-27 NMR was used to investigate AlCl3−MCl (M=Li, Na, K, Butylpyridinium) molten mixtures. In AlCl3 rich mixtures, the27Al resonance line was resolved into two components corresponding to the AlCl 4 − and Al2Cl 7 − species, which were shown to undergo chemical exchange line broadening. This broadening was found to be cation and temperature dependent.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00644889

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