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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 18 (1989), S. 485-491 
    ISSN: 1572-8927
    Keywords: Electrolytic conductivity ; aqueous solutions ; mixed electrolytes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract As part of a cooperative study of the thermodynamic and transport properties of aqueous mixtures of NaCl and MgCl2 at 25°C, we report values of the molar conductivities of the mixed electrolyte in the concentration range 0.5 to 3.6 molar. It was found that the conductivities in the mixtures differ from those calculated assuming additivity of the conductivities of the component binary solutions by 4.65 S-cm2-mol−1 at constant total molarity and 0.50 S-cm2-mol−1 at total ionic strength.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 17 (1988), S. 1059-1065 
    ISSN: 1572-8927
    Keywords: Electrolytic conductivity ; aqueous solutions ; ionic mobility ; magnesium chloride
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract There is a disagreement in the literature regarding the best value of Λo[1/2MgCl2]. For this reason, the conductivity of dilute aqueous MgCl2 solutions have been determined at 25°C. The new experimental data and those available in the literature have been analyzed with two theoretical treatments of electrolytic conductivity. On the basis of that analysis, the values 129.72±0.05 and 53.40±0.05 S-cm2-mol−1 for Λo[1/2MgCl2] and λo[1/2Mg2+], respectively, are recommended.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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