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  • atmospheric lifetimes  (1)
  • sediment chemistry  (1)
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  • 1
    ISSN: 1573-0417
    Schlagwort(e): acid deposition ; Adirondacks ; diatoms ; lake acidification ; paleoecology ; sediment chemistry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie
    Notizen: Abstract Paleoecological analysis of the sediment record of 12 Adirondack lakes reveals that the 8 clearwater lakes with current pH 〈 5.5 and alkalinity 〈 10 μeq l-1 have acidified recently. The onset of this acidification occurred between 1920 and 1970. Loss of alkalinity, based on quanitative analysis of diatom assemblages, ranged from 2 to 35 μeq l-1. The acidification trends are substantiated by several lines of evidence including stratigraphies of diatom, chrysophyte, chironomid, and cladoceran remains, Ca:Ti and Mn:Ti ratios, sequentially extracted forms of Al, and historical fish data. Acidification trends appear to be continuing in some lakes, despite reductions in atmospheric sulfur loading that began in the early 1970s. The primary cause of the acidification trend is clearly increased atmospheric deposition of strong acids derived from the combustion of fossil fuels. Natural processes and watershed disturbances cannot account for the changes in water chemistry that have occurred, but they may play a role. Sediment core profiles of Pb, Cu, V, Zn, S, polycyclic aromatic hydrocarbons, magnetic particles, and coal and oil soot provide a clear record of increased atmospheric input of materials associated with the combustion of fossil fuels beginning in the late 1800s and early 1900s. The primary evidence for acidification occurs after that period, and the pattern of water chemistry response to increased acid inputs is consistent with current understanding of lake-watershed acidification processes.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 115 (1999), S. 219-243 
    ISSN: 1573-2932
    Schlagwort(e): atmospheric lifetimes ; pesticides ; reaction rates ; transformation products
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The current knowledge about transformation rates and products of pesticides in the atmosphere is reviewed. Reactive species and their concentrations in the atmosphere are presented. Reactions of pesticides with these species (including photolysis) in the gas and the particulate phase are evaluated from available experimental data. The potential of estimation methods is discussed. Experimental techniques for laboratory and outdoor measurements are reviewed. Finally, an estimation is made of uncertainties in atmospheric lifetimes due to chemical or physical reactions. It is concluded that the most important transformation of pesticides in the atmosphere is due to reaction with OH radicals. Very few experimental data for pesticides are available though. The levels of uncertainty in OH radical concentrations are acceptable, however, for a proper estimation of atmospheric removal rates due to reactions with OH radicals of those pesticides for which experimental transformation rates (of homologues) are available.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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