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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 26 (1994), S. 361-388 
    ISSN: 1573-8868
    Schlagwort(e): robust M-estimators ; influence function ; background estimation ; robust confidence limits ; separation of mixed sample
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract Samples from hazardous waste site investigations frequently come from two or more statistical populations. Assessment of “background” levels of contaminants can be a significant problem. This problem is being investigated at the U.S. Environmental Protection Agency's Environmental Monitoring Systems Laboratory in Las Vegas. This paper describes a statistical approach for assessing background levels from a dataset. The elevated values that may be associated with a plume or contaminated area of the site are separated from lower values that are assumed to represent background levels. It would be desirable to separate the two populations either spatially by Kriging the data or chronologically by a time series analysis, provided an adequate number of samples were properly collected in space and/or time. Unfortunately, quite often the data are too few in number or too improperly designed to support either spatial or time series analysis. Regulations typically call for nothing more than the mean and standard deviation of the background distribution. This paper provides a robust probabilistic approach for gaining this information from poorly collected data that are not suitable for above-mentioned alternative approaches. We assume that the site has some areas unaffected by the industrial activity, and that a subset of the given sample is from this clean part of the site. We can think of this multivariate data set as coming from two or more populations: the background population, and the contaminated populations (with varying degrees of contamination). Using robust M-estimators, we develop a procedure to classify the sample into component populations. We derive robust simultaneous confidence ellipsoids to establish background contamination levels. Some simulated as well as real examples from Superfund site investigations are included to illustrate these procedures. The method presented here is quite general and is suitable for many geological and biological applications.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Electroanalysis 9 (1997), S. 1005-1008 
    ISSN: 1040-0397
    Schlagwort(e): Quadridentate dihydrogen perchlorate ; Macrocyclic membrane ; Zn2+ ions ; Baby foods ; Soft drinks ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A quadridentate dihydrogen perchlorate macrocyclic membrane is found to exhibit quite promising selectivity for Zn2+. It can be used to estimate zinc in the range 2.5 × 10-6 to 1.0 × 10-1 mol dm-3 (0.16 to 6.50 × 103 mg dm-3) with a near-Nernstian slope of ≍ 28 mV per decade of concentration. The working pH range of the sensor is 3.0 to 7.0. The polystyrene based membrane electrode is found to possess adequate stability and specific selectivity with a response time of 10 s. Most of the ions that interfere with Zn2+ electrode do not cause any significant disturbance with this assembly and the sensor can be used for more than three months in aqueous as well as in partially nonaqueous media. The utility of the membrane sensor has also been observed in solutions contaminated with detergent matter. The membrane sensor has also been used successfully to analyse some baby food products and soft drinks for the determination of Zn2+ ions.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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