ISSN:
1572-9567
Keywords:
bubble-point pressure
;
HCFC 142b (CH3 CClF2)
;
HFC 152a (CH3 CHF2)
;
mixtures
;
refrigerants
;
saturated liquid density
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Forty-eight sets of the saturated liquid densities and bubble-point pressures of the binary HFC 152a + HCFC 142b system were measured with a magnetic densimeter coupled with a variable-volume cell. The measurements obtained at four compositions, 20, 40, 60, and 80 wt%, of HFC 152a cover a range of temperatures from 280 to 400 K. The experimental uncertainties in temperature, pressure, density, and composition were estimated to be within ±15mK, ±20kPa, ±0.2%, and between −0.14 and ±0.01 wt% HFC 152a (−0.01 and + 0.14 wt% HCFC 142b), respectively. The purities of the samples were 99.9 wt% for HFC 152a and 99.8 wt% for HCFC 142b. A binary interaction parameter, k ij , in the Peng-Robinson equation of state was determined as a function of temperature for representing the bubble-point pressures. On the other hand, two constant binary-interaction parameters, k ij and l ij , were introduced into the mixing rule of the Hankinson-Brobst-Thomson equation for representing the saturated liquid densities.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00503517
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