ISSN:
1572-8927
Keywords:
3-Methylsulfolane
;
ionic conductance
;
conductance theory
;
ionic association
;
electrolytes
;
nonaqueous solvents
;
ion size parameters
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract 3-Methylsulfolane is evaluated as an electrolytic solvent utilizing conductance techniques. Conductance data for triisoamylbutylammonium tetraphenylborate and iodide, NaBPh4, KBPh4, NaSCN, KSCN, NaI, and KI were analyzed by the Fuoss-Shedlovsky, Fuoss-Onsager, expanded Pitts, and Fuoss-Hsia treatments. Assocation decreases in the order thiocyanates 〉 iodides 〉 tetraphenylborates. These conductance data at 25°C agree with those obtained in previous investigations of 3-methylsulfolane at 30°C and sulfolane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00647195
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