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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 13 (1979), S. 457-474 
    ISSN: 1573-4889
    Keywords: cobalt-chromium alloys ; oxidation sulfidation ; conjoint attack
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Cobalt alloys containing up to 25% chromium have been exposed to Ar-10% SO2 atmospheres at temperatures between 600 and 1000° C. The results show that, although an increase in chromium content leads to a reduction in the reaction rate, even to negligible rates in the cases of the higher chromium contents, all of the alloys are eventually subjected to rapid attack at more or less longer times, depending on the chromium content. The mechanism of the reaction appears to involve the formation of a more or less protective oxide layer which is eventually penetrated by sulfur. The sulfur forms chromium sulfides at the metal-scale interface, removing the chromium from solution and causing an expansion that cracks the protective scale, allowing both the ingress of gas and the formation of rapidly growing cobalt compounds. The process occurs rapidly with Co-5% Cr alloys, whereas, only the initial sulfur penetration is observed with Co-25% Cr alloys during the time scale of the investigation. The penetration of sulfur is thought to occur as a molecular gas species permeating through the scale down physical defects.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 12 (1978), S. 23-34 
    ISSN: 1573-4889
    Keywords: cobalt ; oxidation ; sulfidation ; conjoint attack
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The attack of cobalt by sulfur and oygen simultaneously in Ar-SO2 atmospheres in the temperature range 500–900°C has been found to conform to the pattern established by the attack of other metals under similar conditions. A thermodynamic and kinetic interpretation of the mechanism has been proposed. The results also indicate that during the initial stages sulfur diffuses through the initially formed oxide layer, eventually leading to formation of the commonly observed duplex sulfide and oxide scale.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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