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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 35 (1991), S. 397-404 
    ISSN: 1573-4889
    Keywords: copper alloys ; nitridation ; kinetics ; scale structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract One of the characteristic features of Mn-Cu binary alloys nitrided by gaseous nitrogen is that one of the two constitutive elements (Mn) can form nitrides, while the other one (Cu) does not give any stable compound with nitrogen. The only mixed manganese-copper nitride is the CuMn 3 N compound. The reaction kinetics with nitrogen are very slow and there is no internal nitriding. For alloys containing less than 20 at.% Mn, nitrogen reacts very little. The nitride scale formed on the alloys of greater Mn concentrations is a mixed nitride whose formula is Cu 1−x Mn 3+x N. The techniques of examination used are SEM, EMA, and GDS analysis.
    Type of Medium: Electronic Resource
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