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  • critical molecular weight  (1)
  • morphology  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1809-1813 
    ISSN: 0887-6266
    Keywords: slow crack growth ; polyethylene ; critical molecular weight ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An ethylene-hexene copolymer was fractionated into five fractions and the density of short-chain branches was measured for each fraction. The slow crack growth behavior was measured on each fraction by sandwiching the small amount of fractionated resin of about 0.2 g between polyethylene grips. The resistance to slow crack growth was negligible for the three fractions whose Mw was less than 1.5 × 105. For the fourth fraction with Mw greater than 1.5 × 105, the resistance to slow crack growth was very high, being greater than that for the whole resin even though its density of short-chain branches was less than that of the whole resin. It is concluded that a molecular weight greater than 1.5 × 105 is required to create the number of tie molecules that is necessary to produce a high resistance to slow crack growth in this particular copolymer. © 1996 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 767-772 
    ISSN: 0887-6266
    Keywords: polyethylene ; slow fracture ; morphology ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The slow crack growth behavior of a linear polyethylene with different morphologies was studied by using three point bending with a single edge notched specimen at testing tem-peratures from 30 to 80°C. The morphology was varied by annealing the quenched material at temperatures from 86°C to 135°C. It was found that at test temperatures of 60°C or less, the changes in failure time with annealing temperature are very similar to the change in density with a maximum at 130°C. At testing temperatures above 60°C, the relationship of between failure time and annealing temperature is altered when the test is in the range of the α transition temperature. These results indicate that with respect to slow crack growth in the case of a homopolymer the strength of the crystals is relatively more important than the number of tie molecules. © 1993 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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