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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 19 (1998), S. 481-490 
    ISSN: 1572-9567
    Keywords: critical point ; temperature control ; temperature gradients ; thermostat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The density of a pure fluid near its critical point is extremely sensitive to temperature gradients. In the absence of gravity, this effect limits the fluid's homogeneity. For example, at 0.6 mK above the critical temperature, the microgravity experiment Critical Viscosity of Xenon (CVX) can allow temperature differences no larger than 0.2 μK, corresponding to a gradient of 10−5 K·m−1. The CVX thermostat, which consists of a thick-walled copper cell contained within three concentric aluminum shells, was designed to achieve such a small temperature gradient. However, asymmetries not included in the thermostat's model could degrade the thermostat's performance. Therefore we measured the temperature gradient directly with a miniature commercial thermoelectric cooler consisting of 66 semiconductor thermocouples. We checked the results with a half-bridge consisting of two matched thermistors. The measurement was made along a thin-walled stainless-steel cell whose conductance was much lower than that of the copper cell, thus “amplifying” the temperature differences by a factor of 60. When the thermostat was controlled at a constant temperature, the steel cell's static temperature difference was 5±1 μK. (The value inferred for the copper cell is 0.08 μK.) Ramping the thermostat's temperature at a rate of 1 × 10−5 K·s−1 increased the temperature difference to 0.36 mK. These results demonstrate the feasibility of achieving extremely low temperature gradients.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 7 (1986), S. 675-686 
    ISSN: 1572-9567
    Keywords: critical point ; cyclohexane ; methanol ; torsion oscillator ; viscometer ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A torsion-oscillator viscometer has been constructed for the measurement of the viscosity of fluids near both liquid-vapor and liquid-liquid critical points. This viscometer has a resolution of ±0.2% and operates at a low frequency (0.6 Hz) and a very low shear rate (0.05 Hz). Thus, it can be used closer to critical points than other viscometers before encountering the non-Newtonian phenomena associated with critical slowing down. This viscometer was used to study the viscosity anomaly near the consolute point of mixtures of methanol and cyclohexane along paths of constant pressure and paths of constant volume at temperatures spanning the range 10−5 〈 (T-T c)/T c〈10−2. The data are consistent with a simple, power-law divergence of the viscosity with a multiplicative background characterized by an apparent exponent y≈0.041. Recent theoretical estimates for y are near 0.033. If the data are to be fit with the theoretical value of y, one must simultaneously restrict the range of the data and introduce additional unphysical parameters into the fitting function.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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