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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 3 (1971), S. 323-330 
    ISSN: 1572-9613
    Keywords: Surface tension ; scaling laws ; droplet model ; critical point
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An expression for the pressure is proposed which leads to a symmetric equation of state for liquid and gas near the critical point. Our “bubble-droplet” formula is similar to Fisher's cluster expansion but contains an additional term due to the density dependence of the surface tension. Also, it assumes the density difference between a droplet (or bubble) and the surrounding medium to be proportional tol − 1/δ and not to be independent of the droplet sizel. Then, the scaling homogeneity assumption and some scaling laws, includingdν=2−α, can be derived (d is dimensionality). The additional assumption of spherical droplets and bubbles leads to a new scaling law 1+β=(d−1)ν, which is only slightly violated in the lattice gas ford=2, 3, 4.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 6 (1972), S. 49-59 
    ISSN: 1572-9613
    Keywords: Monte Carlo ; lattice gas ; surface area ; surface tension ; droplet model ; critical point ; scaling laws ; nucleation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Computer simulation of droplets containingl molecules (l ⩽ 1000) in a lattice gas shows that the average surface area is proportional tol σ′;σ′≃ 0.6 in two and σ′= 0.825 in three dimensions for small droplets. These exponents agree approximately with those in Kadanoff's modification of Fisher's droplet model near critical points [σ′= (1 + β)/βδ; ourT/T c is 0.4, 0.7, and 0.9]. For larger droplets, these exponents change to 1/2 (d = 2) and 2/3 (d = 3), the transition occurring for droplet diameters larger than the coherence length and smaller than the critical diameter in the nucleation of supersaturated vapors. This latter result rises some doubts on a recent nucleation theory of Eggingtonet al.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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