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  • Chemistry  (10)
  • High-temperature superconducting thin film  (2)
  • crystal field theory  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Physics and Chemistry of Solids 55 (1994), S. 647-650 
    ISSN: 0022-3697
    Keywords: Cr^3^+ ion ; Electron paramagnetic resonance ; MgTiO"3 ; crystal field theory ; impurity environment
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Physics and Chemistry of Solids 53 (1992), S. 1017-1019 
    ISSN: 0022-3697
    Keywords: Cs"3ZnCl"5 ; Electron paramagnetic resonance ; crystal field theory ; superposition model ; zero-field splitting
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1572-9605
    Keywords: High-temperature superconducting thin film ; pulsed laser ablation ; buffer layer ; sapphire substrate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract YBa2Cu3O7 superconducting thin films were deposited onR-plane sapphire substrates with Yttria-stabilized zirconia buffer layer by laser ablation. The structure of the films was characterized by X-ray diffraction. Superconducting transitional temperatures as high as ≥90 K and critical current densities up to 2.2×106 A/cm2 (77 K) were achieved. The results of Auger depth profile showed that no obvious diffusion occurred between the substrate and the YBa2Cu3O7 thin film.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1572-9605
    Keywords: High-temperature superconducting thin film ; pulsed laser ablation ; heater ; composite scanning ; large area
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We report on the successful preparation of large-area high-quality YBa2Cu3O7 superconducting thin films by pulsed excimer laser ablation with a Si heater and composite scanning of laser beam and target. The Si heater, composite scanning of laser beam and target, and experiment results are described. The temperature variation of the Si heater was 〈 ±0.5% in a 45×40 mm2 area of 900–1000 °C. Films were deposited on LaAlO3 substrates 35 mm in diameter. The thin films exhibited a thickness variation of ±2.5%; the superconducting properties wereT c0=91×0.5 K andJ c= (3.3±0.7)×106 A/cm2 at 77 K and zero magnetic field.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2395-2400 
    ISSN: 0887-624X
    Keywords: pseudo IPNs ; PCU ; CR ; conducting polymer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A number of pseudo IPNs of poly(carbonate-urethane) (PCU) and crosslinked polychloroprene (CR) have been synthesized and characterized. The single phase morphology of these novel pseudo IPNs has been confirmed by DSC measurements and electron microscopy. The room temperature electrical conductives of homopolymers and pseudo IPNs have been investigated for both undoped and iodine-doped samples. © 1994 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 1317-1322 
    ISSN: 0887-624X
    Keywords: pseudo IPNs ; NR ; PCU ; conducting polymers ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Recent DC conductivity measurements on iodine-doped full and psuedo IPNs of poly (carbonate-urethane) (PCU) and natural rubber (NR) reveal that these materials possess a modest conductivity. Both such full and pseudo IPNs (with linear NR chains) are single-phased materials if the NR is of sufficiently high molecular weight derived from Brazilian Manihot glaziovii. On iodine doping the electrical conductivity rises eight orders of magnitude of both the full IPN (to ca. 10-5S cm-1) and the pseudo IPN (to ca. 10-4 S cm-1). A simple theory based on the assumption that conduction occurs essentially along the linear NR chains, composing a percolation cluster, in the iodine-doped pseudo IPNs of PCU and NR accounts for the observed electrical conductivity dependence on temperature, iodine molality, and weight fraction of NR. As temperature decreases the DC conductivity falls and the material becomes essentially an insulator. At sufficiently low temperature (ca. 115 K) this trend reverses and the DC conductivity rises by two orders of magnitude with further decreasing temperature up to that of liquid helium. © 1994 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2055-2057 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1695-1701 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A variety of polyorganosiloxanes containing dimethyl, diphenyl, and methylphenyl substituents were studied to determine transparency and optical radiation hardness. Siloxanes show superior optical radiation hardness when compared to optical thermoplastics such as PMMA. Transparency is diminished in polymers containing diphenyl units. This is attributed to the inability to remove traces of the crystalline monomer. Methylphenyl polymers are highly transparent. The maximum attainable refractive index in transparent systems is 1.53.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 1429-1437 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The crystal orientation distribution in injection-molded bars made from several polypropylene compounds has been investigated using pole figure analysis. The fillers used were glass fibers, chalk, and talc, and some compounds contained one filler and others contained glass fibers plus one or both of the others. All compounds showed strong orientation in the skin with the b-axis of the monoclinic crystals lying preferentially normal to the flow direction and in many cases parallel to the normal to the bar face. This normal direction orientation was very strong in compounds containing talc and is probably caused by crystals forming with their (010) planes on the talc platelet faces, which align themselves parallel to the mold face. Strong orientation persists into the interior of the moldings containing talc, whereas in the other compounds, the orientation at intermediate depths is much less pronounced than in the skin. © 1992 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 92-99 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The phase behavior of polymer blends under simple shear flow has been studied using a custom-designed rheo-optical system consisting of a two-dimensional small-angle light scattering (SALS) device incorporated into a conventional rheometer. Two-dimensional SALS images were gathered for model polymer blend systems with different quiescent phase behavior: polystyrene/polyisobutylene (PS/PIB) that exhibits upper critical solution temperature phase behavior and polystyrene/poly(vinyl methyl ether) (PS/PVME) that shows lower critical solution temperature phase behavior. For the PS/PIB blend, shear-induced phase mixing occurred at a critical shear rate. Below that critical shear rate, the dispersed phase was highly elongated parallel to the flow direction. For PS/PVME blends, a streak scattering pattern was observed even though the sample became optically clear after shearing. We observed, apparently for the first time, the development of a bright-streak pattern from a transient dark-streak pattern for a polymer blend system under shear. Rheo-microscopy studies revealed an intriguing wave pattern that developed coincident with the observation of a streak pattern by SALS. The relationship between the two phenomena has not yet been established.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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