ISSN:
1572-8951
Keywords:
Non-topochemical reaction
;
crystal structure
;
lattice energy calculations
;
thermal motion analysis
;
disorder
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The molecular and crystal structure of 2,5-dibenzylidenecyclopent-3-ene-1-one has been studied in detail to explain the formation of a non-topochemical pseudo-mirror-symmetric dimer upon photoirradiation. Packing energy calculations, analysis of the thermal motion, and lattice energy calculations are employed to analyse and understand the observed dimerization reaction, crystal structure, and crystal properties.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00999702
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