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  • 1995-1999  (3)
  • 1960-1964
  • current efficiency  (2)
  • Darcian model  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 28 (1998), S. 915-920 
    ISSN: 1572-8838
    Keywords: Zinc electrowinning ; antimony ; triethylbenzylammonium chloride ; current efficiency ; polarization ; morphology ; power consumption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The effects of triethylbenzylammonium chloride (TEBACl) on the electrowinning of zinc from acidic sulfate solutions have been studied in the presence and absence of antimony(iii). The factors considered included the current efficiency (CE), power consumption, polarisation behaviour, and the crystallographic orientations and surface morphology of the deposits. Compared with the traditional industrial additive, glue, the addition of TEBACl increased CE, reduced power consumption and improved the surface morphology. Maximum CE and minimum power consumption were obtained at 2mgdm−3 TEBACl and 0.01mgdm−3 Sb(iii). The exchange current density, Tafel slope and transfer coefficient were determined to elucidate the nature of the electrode reactions involved.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 1229-1235 
    ISSN: 1572-8838
    Keywords: additive ; antimony ; current efficiency ; power consumption ; zinc electrowinning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The effects of the organic additives cetyltrimethylammonium bromide (CTABr) and tetrabutyl ammonium bromide (TBABr) on the electrowinning of zinc from acidic sulphate solutions were studied in the presence and absence of trace amounts of antimony(iii). The results indicated that CTABr has similar properties to the commonly used industrial additive glue with respect to current efficiency, power consumption, polarization behaviour, and the crystallographic orientation and surface morphology of the zinc deposits. TBABr was generally less useful with respect to all these properties. Voltammetric studies indicate that polarisation for zinc electrodeposition decreased in the order CTABr 〉 glue 〉 TBABr. The nature of the electrode reactions were investigated through measurements of exchange current densities, Tafel slopes and transfer coefficients.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 633-661 
    ISSN: 0271-2091
    Keywords: free convection ; porous enclosure ; Darcian model ; wavy surface ; finite element method ; numerical study ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The coupled streamfuction-temperature equations governing the Darcian flow and convection process in a fluid-saturated porous enclosure with an isothermal sinusoidal bottom sun face, has been numerically analyzed using a finite element method (FEM). No restrictions have been imposed on the geometrical non-linearity arising from the parameters like wave amplitude (a), number of waves per unit length (N), wave phase (Φ), aspect ratio (A) and also on the flow driving parameter Rayleigh number (Ra). The numerical simulations for varying values of Ra bring about interesting flow features, like the transformation of a unicellular flow to a multicellular flow. Both with increasing amplitude and increasing number of waves per unit length, owing to the shift in the separation and reattachment points, a row-column pattern of multicellular flow transforms to a simple row of multicellular flow. A cycle of n celluar and n+1 cellular flows, with the flow in adjacent cells in the opposite direction, periodically manifest with phase varying between 0 and 360°. The global heat transfer into the system has been found to decrease with increasing amplitude and increasing number of waves per unit length. Only marginal changes in the global heat flux are observed, either with increasing Ra or varying Φ. Effectively, sinusoidal bottom surface undulations of the isothermal wall of a porous enclosure reduces the heat transfer into the system. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
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