ISSN:
0887-624X
Keywords:
2-methylene-1,3-dioxane
;
4-methyl-2-methylene-1,3-dioxane
;
4,4,6-trimethyl-2-methylene-1,3-dioxane
;
2-methylene-1,3-dioxolane
;
4-methyl-2-methylene-1,3-dioxolane
;
4,5-dimethyl-2-methylene-1,3-dioxolane
;
cationic copolymerization
;
reactivity ratio
;
relative reactivity
;
ring-retained polymerization
;
cyclic ketene acetals
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Cationic copolymerizations of 4-methyl-2-methylene-1,3-dioxane, 2 (M1), with 2-methylene-1,3-dioxane, 1 (M2); of 4,4,6-trimethyl-2-methylene-1,3-dioxane, 3 (M1), with 2-methylene-1,3-dioxane, 1 (M2); of 4-methyl-2-methylene-1,3-dioxolane, 5 (M1), with 2-methylene-1,3-dioxolane, 4 (M2); and of 4,5-dimethyl-2-methylene-1,3-dioxolane, 6 (M1), with 2-methylene-1,3-dioxolane, 4 (M2) were conducted. The reactivity ratios for these four types of copolymerizations were r1 = 1.73 and r2 = 0.846; r1 = 2.26 and r2 = 0.310; r1 = 1.28 and r2 = 0.825; r1 = 2.23 and r2 = 0.515, respectively. The relative reactivities of these monomers towards cationic polymerization are: 3 〉 2 〉 1; and 6 〉 5 〉 4. With both five- and six-membered ring cyclic ketene acetals, the reactivity increased with increasing methyl substitution on the ring. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 861-871, 1998
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
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