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Redox responsive metal complexes containing cation binding sites (1987)

Beer, Paul D. ; Jones, Christopher J. ; McCleverty, Jon A. ; [et al.]

Springer

Journal of inclusion phenomena and macrocyclic chemistry 5 (1987), S. 521-524

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ISSN: 1573-1111

Keywords: Molybdenum ; nitrosyl ; pyrazolylborate ; electrochemistry ; cyclic polyether ; complexation ; sodium ; potassium

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract A series of cyclic polyethers, which incorporate the redox active {Mo(NO)}3+ moiety, have been prepared and characterised. The electrochemistry of these complexes has been investigated and their reduction potentials found to undergo anodic shifts upon the binding of alkali metal cations to the cyclic polyether moiety. The magnitude of the shift appears relatively insensitive to the size of the cyclic polyether ring, but is substantially reduced when K+ is used in place of Na+.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00664111

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