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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 57 (1989), S. 937-963 
    ISSN: 1572-9613
    Keywords: Coexistence curve ; critical point ; dew/bubble curve ; phase transitions ; polydisperse ; series expansions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We describe two new methods for locating the dew/bubble curves of fluids. One is a numerical method and the other an analytical method based on the use of series expansions. The utility of these two methods is illustrated by application to a simple one-component fluid model and to several model polydisperse fluids. The numerical method is based on a new geometric representation of the equilibrium conditions-similar in spirit to the geometric representations often used for solving the equilibrium conditions of pure fluids. Our calculations show that the series-expansion technique can be quite effective at producing accurate representations of the phase boundaries.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 10 (1989), S. 75-85 
    ISSN: 1572-9567
    Keywords: coexistence curve ; critical point ; dew/bubble curve ; phase transitions ; polydisperse
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new geometric representation for the dew/bubble conditions of a special class of polydisperse fluids is used to develop series expansion representations for the location of the top of the dew/bubble and shadow curves and for an expansion around the top of the dew/bubble and shadow curves. An excellent approximation for the one-comonent van der Waals coexistence is given as a special illustration of the method.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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