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  • 1
    Electronic Resource
    Electronic Resource
    Reatarding effect of nitrogen ylide for the polymerization of N-vinyl pyrrolidone (1990)
    Springer
    Colloid & polymer science 268 (1990), S. 645-648 
    Details
    ISSN: 1435-1536
    Keywords: β-picolinium-p-chlorophenacylide ; α-α azobisisobutyronitrile ; N-vinyl pyrrolidone ; dilatometry ; retarder ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract β-Picolinium-p-chlorophenacylide (β-PCFY) acts as a retarder for polymerization of N-vinyl pyrrolidone. The polymerization runs were carried out at 60°C using benzene as an inert solvent. The kinetic equation for the present system may be written asR p α[β-PCPY]−1.0 [AIBN]0.66[N-VP]1.0. The value of overall energy of activation for polymerization in presence and absence ofβ-PCPY was computed as 44.0 and 42.3 kJ mol−1, respectively. The inverse relationship ofR p and¯M v withβ-PCPY suggests thatβ-PCPY acts as a polymerization retarder. The retarding effect is also evidenced by higher initiator exponent value and higher value of energy of activation in presence of ylide. A mechanism is also proposed in which polymer propagating chain combines with one ylide component to give resonance stabilized radical.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01410406
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  • 2
    Electronic Resource
    Electronic Resource
    Copolymerization of zinc acrylate with acrylonitrile initiated by As2S3-styrene complex (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 34 (1994), S. 105-109 
    Details
    ISSN: 0959-8103
    Keywords: Zinc acrylate ; acrylonitrile ; As2S3-styrene complex ; copolymerization ; dilatometry ; kinetics ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Radical copolymerization of zinc acrylate (ZnA2) with acrylonitrile (AN), initiated by As2S3-styrene complex(I), in dimethyl Sulphoxide (DMSO) at 90 ± 0.1°C for 1.0h under inert atmosphere, yields non-alternating copolymers. The kinetic expression is Rp ∝ [I]0.33 [ZnA2]0.25 [AN]0.44, i.e. the system follows non-ideal kinetics, which is due to primary radical termination as well as degradative chain transfer reactions. The values for activation energy (E) and k2p/kt are 128kJ mol-1 and 8.57 × 10-7 litre mol-1 s-1, respectively. Thermal stability, solubility in different solvents, and IR and NMR spectra have been evaluated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pi.1994.210340114
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    Paper (German National Licenses)
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