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Digitale Medien

The quadruply bondedbis-carboxylatescis-Re2(μ-O2CCH3)2X4L2 (X = halide;L = neutral donor) as synthons in dirhenium chemistry (1994)

Walton, Richard A.

Springer

Journal of cluster science 5 (1994), S. 173-184

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Details

ISSN: 1572-8862

Schlagwort(e): Rhenium ; dimetal comptexes ; phosphine ligands ; carboxylatebridged complexes ; redox chemistry ; preparation ; structure

Quelle: Springer Online Journal Archives 1860-2000

Thema: Maschinenbau , Physik

Notizen: Abstract The reactions of the quadruply bonded dirhenium(III) carboxylatescis-Re2(μ-O2CR)2X4L2 (X=CI or Br; L=a monodentate donor) with monodentate, bidentate, and tridentate phosphine donors result in several types of redox behavior, usually involving partial or complete reductive decarboxylation of the dirhenium unit. Examples of dirhenium(VI, II), dirhenium(IV, II), dirhenium(III, II), and dirhenium(II, II) complexes, in which Re-Re bond orders of 4, 3.5, 3, l, or zero are encountered, have been isolated and repre-sentative examples structurally characterized. The course of these reactions is dependent upon the nature of the phosphine. The scope of this remarkably rich chemistry is discussed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01165498

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