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In vitro nitrosation of ephedrine in the presence of cyclodextrins (1987)

Wedelich, V. ; Mehnert, W. ; Frömming, K. -H.

Springer

Journal of inclusion phenomena and macrocyclic chemistry 5 (1987), S. 621-624

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ISSN: 1573-1111

Keywords: Nitrosation reactions ; α-, β-, γ-cyclodextrin ; dimethyl-β-cyclodextrin ; ephedrine ; nitrosoephedrine

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract β-, and γ-cyclodextrin and heptakis-2,6-di-O-methyl-β-cyclodextrin enhance the nitrosation rate of l-ephedrine if the nitrosation assay procedure (NAP test) is applied. During this reaction with β-cyclodextrin a solid inclusion compound of β-cyclodextrin andN-nitrosoephedrine precipitates. Solubilities and stabilities of inclusion compounds of the cyclodextrins with ephedrine and nitrosoephedrine, respectively, explain especially the catalytic effects of some cyclodextrins on ephedrine.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00663002

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