ISSN:
1588-2837
Keywords:
aquated Fe(III) complex
;
dimethylformamide
;
laser flash photolysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Laser flash photolysis was used to study the photochemistry of Feaq 3+ complex in aqueous solutions with additions ofN,N-dimethylformamide. An electronic absorption band with a maximum at 380 nm belonging to the*CH2(CH3)NCHO radical was recorded. The recombination (or disproportionation) rate constants of*CH2(CH3)NCHO radicals and their reaction with the Feaq 3+ complex were estimated to be (3.4±0.8)×109 M−1s−1 and (4.3±0.6)×107 M−1s−1, respectively. The mechanism of radical formation is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02475756
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