ISSN:
1572-8927
Keywords:
Heats of solution
;
heat capacity
;
dipole moments
;
static permittivity
;
carbohydrates
;
dielectric relaxation
;
sugar conformation
;
alcohols
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The effect of hydroxyl substitution on the nature of the hydration of an alkane chain has been studied by calorimetric techniques. Static permittivities (ɛ0) of a range of monosaccharides and related compounds in aqueous solution have also been determined. The (ɛ0) data, suitably processed, have provided information about the solute dipole moments. In conjunction with earlier results from volumetric, compressibility, and relaxation studies, the specific hydration model is further developed and the relationships between solute molecular conformations and solute-water interactions are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00651968
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