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  • 1
    ISSN: 1435-1536
    Keywords: Dielectric property ; dielectric relaxation ; permittivity ; electrical conductivity ; ion-exchanger
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Ion-exchange beads with different densities of fixed charges were prepared by sulfoethylation of dextran gel beads. The relative permittivities and the electrical conductivities of the ion-exchange beads in a sodium form were evaluated by a dielectric technique consisting of the following two procedures proposed in a previous study (2): (a) Dielectric measurements for densely packed sediments of the ion-exchange beads; (b) Analysis of the observed dielectric relaxations by means of a theoretical equation of interfacial polarization for suspensions of spherical particles. The deduced permittivities of the ionexchange beads in equilibrium with water were about 60, which is lower than those of outer aqueous phases. The deduced conductirities were of the order of 1 to 10 mS cm−1 and were increased reasonably with the fixed charge density. Closer consideration on these deduced values indicates that no specific interaction exists between the counter ions and the fixed charges irrespective of changes in fixed charge density and temperature.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 262 (1984), S. 477-480 
    ISSN: 1435-1536
    Keywords: Dielectric property ; permittivity ; electrical conductivity ; ion-exchanger ; interfacial polarization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Dielectric measurements were carried out for dense sediments of quaternary ammonium type anion-exchange resin beads dispersed in deionized water over a frequency range of 30 Hz to 130 MHz. According to a method proposed in previous studies the relative permittivities and electrical conductivities of ion-exchange beads were evaluated from the relaxation data observed in a megahertz region on the basis of a theory of interfacial polarization. The permittivities of the ion-exchange beads were found to be unchanged irrespectively of the salt form and somewhat lower than that of a continuous medium, while the conductivities of the ion-exchange beads were characteristic of the salt form. The equivalent ionic conductances of different counter anions in the beads were estimated from the conductivities of the ion-exchange beads. These results indicate an ion-binding effect in the resin beads.
    Type of Medium: Electronic Resource
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