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  • emulsion polymerization  (4)
  • Anoectochilus koshunensis  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 33 (1993), S. 1133-1137 
    ISSN: 0031-9422
    Keywords: 3,4-dihydroxy butanoic acid ; 3-glucosyloxybutanolide ; Anoectochilus koshunensis ; Orchidaceae ; glucoside ; glucosyl-3-pyridinemethanol ; kinsenoside ; nicoloside.
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 36 (1994), S. 1465-1467 
    ISSN: 0031-9422
    Keywords: 2'-deoxyadenosine ; 26-methylstigmasta-5,22,25,(27)-trien-3β-ol. ; Anoectochilus koshunensis ; Orchidaceae ; anoectosterol ; megastigmane glucoside ; sterol
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 274 (1996), S. 801-804 
    ISSN: 1435-1536
    Keywords: Multihollow particles ; emulsion polymerization ; morphology ; carboxyl group ; alkali swelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Submicron-sized styrene-methacrylic acid copolymer particles, which were produced by emulsion copolymerization, were changed to those having multihollow structure by treating stepwise the emulsion as follows. First alkali treatment was carried out at higher temperature than the glass transition temperature and subsequently the emulsion was cooled by keeping it at room temperature. This was named “alkali/cooling method”. The effects of methacrylic acid content, pH, time and temperature in the alkali treatment on the formation of multihollow structure were clarified.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 275 (1997), S. 82-85 
    ISSN: 1435-1536
    Keywords: Key words Multi-hollow particle ; emulsion polymerization ; morphology ; carboxyl group ; alkali swelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The effects of molecular weight, particle diameter and cooling condition on the formation of multi-hollow structure formed within submicron-sized styrene-methacrylic acid copolymer particles by the “alkali/cooling method” proposed by the authors were examined and the formation mechanism was proposed. The original particles were produced by emulsion copolymerization in the presence of n-octyl mercaptan as a chain transfer agent.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1435-1536
    Keywords: Multihollow particles ; emulsion polymerization ; morphology ; carboxyl group ; transition temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Submicron-sized multihollow styrene-methacrylic acid (92.6/7.4, molar ratio) copolymer particles having high transition temperature above 100°C were produced by using the stepwise alkali/acid method proposed by the authors. The original particles were prepared by emulsion copolymerization of styrene and methacrylic acid. The effects of pH, temperature and time in the alkali treatment process as the first step on the multihollow structure were clarified under the same acid treatment conditions.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1435-1536
    Keywords: Key words Carboxyl group ; emulsion polymerization ; nanoparticles ; microsphere ; emulsifier
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Styrene-methacrylic acid copolymer (P(S-MAA)) nanoparticles having high Tg were produced by a dissolution of submicron-sized P(S-MAA) particles as follows. Submicron-sized P(S-MAA) particles having various MAA contents were produced by emulsion copolymerization. Secondly, they were treated in a polyoxyethylene nonylphenyl-ether nonionic emulsifier aqueous solution at pH 13.0 and above 90 °C. The nanoparticles having about 30 nm in diameter were only produced from the particles having MAA contents around 7 mol%, and above the contents, they were not produced. It seems to be based on that emulsifier molecules are not adsorbed onto the polymer molecules enough to dissolve them. The effect of MAA content on such a dissolution behavior was examined using seven kinds of different nonionic emulsifiers having hydrophile-lipophile-balance values between 12.2 and 18.2 at various temperatures and initial pH.
    Type of Medium: Electronic Resource
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