ISSN:
0021-8995
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
The water-soluble solids comprised of the ionic complex between chitosan and acetic acid, chitosonium acetate, are converted into chitin by heating. The thermally-induced conversion of a water-soluble chitosonium acetate in film form into a water-insoluble chitin film was examined by thermal analysis (DMTA, TGA, DSC, and TMA) and by solid state 13C-NMR spectroscopy. Results indicate that tan δ-transitions occur at increasingly high temperatures, and over progressively wider temperature ranges, as the transformation progresses. Likewise, the storage modulus, log E′, increases as the chitosonium acetate film undergoes “cure” and converts to chitin. Cure kinetic parameters are obtained using the model proposed by Provder et al. modified for glass transition temperature (Tg). The results suggest the existence of two sequential first order reactions, an initial and a late cure reaction, having activation energies of approximately 15 and 21 kcal/mol, respectively. © 1996 John Wiley & Sons, Inc.
Zusätzliches Material:
18 Ill.
Materialart:
Digitale Medien
Permalink