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Substitutive sulfotrioxidation of branched perfluoroolefins (1992)

Cherstkov, V. F. ; Sterlin, S. R. ; German, L. S.

Springer

Russian chemical bulletin 41 (1992), S. 1836-1840

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ISSN: 1573-9171

Keywords: fluoroolefins ; perfluoroalken-2-yl fluorosulfates ; perfluoroalkenoyl fluorides

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract We have studied the insertion of SO3 into the C-F bond of perfluoroolefins under conditions of electrophilic catalysis. It was shown that sufficiently high allylic mobility of the fluorine atoms is only preserved when in the allylic triad, in addition to the substituted fluorine; also not less than three fluorine atoms are present in the α and γ positions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00863819

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