ISSN:
1573-9171
Keywords:
electrolysis
;
fluorosulfatohalogenation
;
stable radical
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A study has been made of the electrochemical fluorosulfation of perfluoro-2-alkenes in the presence of halogens, leading to the formation of fluoroaliphatic vicinal fluorosulfatohalides. The reaction proceeds as a conjugate radical addition of peroxydisulfuryl difluoride and the halogen at the double bond of the olefin; the ratio of the resulting regioisomers is determined by steric factors.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01150910
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