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  • 1995-1999  (2)
  • 81.10  (1)
  • fullerene dimers  (1)
  • 1
    ISSN: 1432-0630
    Keywords: 68.35 ; 81.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract C70 single crystals, free from solvent contamination, were grown via vapor phase transport technique. The (0001) face of the C70 crystal was imaged with Atomic Force Microscopy (AFM) under ambient atmosphere. Low-resolution images of a freshly prepared crystal revealed well-ordered faceted regions with multiple terraces extending over a region of several hundred square nanometers. The terraced structure in the images indicates that the crystals formed as a layer growth. In the high-resolution images, C70 molecules were resolved in a hexagonal close packed (hcp) structure with an average center-to-center distance of 10.5±0.5 Å. After one month's exposure to the ambient atmosphere, the molecules rearranged into a mixed structure consisting of hcp and face centered cubic (fcc) regions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 167-173 
    ISSN: 1572-8943
    Keywords: fullerene dimers ; [60]fullerene ; thermal decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition of methano-fullerene derivatives such as ethoxycarbonyl methano[60] fullerene and various isomers of bis-(ethoxycarbonyl methano)[60] fullerene leads to new fullerene derivatives, which have been preliminary characterized. The analysis of separated species was performed by UV-VIS, IR, H- and C-NMR, STM, FAB, LDI and MALDI-TOF MS spectroscopy. One of the isolated phases is a C122 molecule with a dumbbell-like structure.
    Type of Medium: Electronic Resource
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