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  • 76.60  (1)
  • heavy fermions  (1)
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Erscheinungszeitraum
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 49 (1989), S. 65-68 
    ISSN: 1432-0630
    Schlagwort(e): 66.30 ; 76.60
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract The relaxation timesT 1,T 1q,T 1D, andT 2 for1H in the tetragonal-A phase of HxWO3 have been measured over the temperature range 190 to 490 K. The1H relaxation behaviour appears to be governed by diffusion over inequivalent jump distances, approximating to a short range planar diffusion and a long range isotropic diffusion. Parameters for the latter motion are estimated asE a = 68 kJ/mol andτ 0=2.5×10−13 s. The powder X-ray diffraction pattern for this phase of HxWO3 has been studied over the temperature range 300–470 K. The tetragonal distortion diminishes with temperature and H0.43 WO3 becomes cubic at about 435 K. Volumetric studies of hydrogen evolution show that decomposition accelerates at approximately this temperature.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity 13 (2000), S. 793-796 
    ISSN: 1572-9605
    Schlagwort(e): heavy fermions ; spinodal segregation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract Two equilibrium bond lengths coexist in the (001) CuO2 planes of the copper-oxide superconductors; (Cu–O)loc 〉 (Cu–O)itin correspond, respectively, to the antiferromagnetic parent and overdoped phases. In the range 0 〈 p ≤ 0.1 holes/Cu atom of these planes, each hole occupies an itinerant-electron cluster of 5 to 6 Cu atoms in a (CuO)loc matrix at temperatures T 〉 T*; below T*, a spinodal phase segregation between parent and vibronic phases occurs. Evidence is cited for a condensation in the vibronic phase on lowering the temperature to one hole per 3 Cu atoms in alternate Cu–O–Cu rows. Ordering of the holes at a $$p_c \simeq \tfrac{1}{6}$$ leads to the formation of itinerant vibronic states, and BCS coupling of the heavy fermions below T c gives a superconductive condensate of symmetry $${\text{d}}_{x^2 - y^2 } $$ .
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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