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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 198 (1998), S. 117-125 
    ISSN: 1573-5036
    Keywords: diffusion ; humic substances ; mass flow ; metal complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The influence of fulvic acid (FA) on the porous system self diffusion coefficient (Dp) of Fe in Calciorthent soils of Bihar, India, was determined with the half cell technique. Significantly higher values of Dp were observed when Fe was applied as Fe–FA to the soil compared to FeCl3. The capacity factor of Fe decreased considerably due to its complexation by fulvic acid, resulting in an increase in the Dp of Fe. The organic carbon content of the soils correlated positively with Dp of Fe while it showed a negative relationship with active CaCO3 and the clay content of soils. A soil culture system simulating acquisition of Fe by rice was developed to investigate transport of Fe from the soil solution to the surface of the plant roots through diffusion and mass flow. Mass flow contributed only 5–9% of the total Fe uptake by rice, with the remainder being ascribed to diffusion and root interception. A significant relationship ( r =0.96**) between Dp- and Fe-uptake by rice was observed. The uptake of Fe by the crop and the percentage of tissue iron content derived from fertilizer were higher in the case of Fe–FA in comparison with FeCl3, indicating the superiority of organically complexed Fe fertilizers over inorganic salts.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 223 (2000), S. 13-21 
    ISSN: 1573-5036
    Keywords: Fe3+ complexes ; fulvic acid (FA) ; humic substances ; stability constants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The stability constants of complexes formed between iron (III) and fulvic acid extracted from organic manures and wastes such as urban domestic sewage sludge, farmyard manure, poultry manure and sulfitation pressmud were investigated by the potentiometric titration method in an ionic medium of 0.1 M KNO3 at 25±1 °C. A modification of the Katchalsky's model was employed for the estimation of stability constants. The displacement of the titration curves due to presence of Fe3+ in FA solutions formed the basis of calculations. The weak acidic property of fulvic acids due to carboxyl groups resulted in buffering over a wide range of pH; fulvic acids were completely neutralized in the pH range of 7.00–8.85. Apparent dissociation constants (pKAPP) of weakly acidic carboxyl groups were a direct function of degree of dissociation (αL) in the mid-range of titration curves but were non-linear at high and low αL values. The stability constants for formation of Fe–FA complexes (log βFe) calculated from the titration data were in the range of 5.64–7.55, depending upon αL and electrostatic properties of fulvic acids. The relatively high stability constants of Fe–FA complexes in comparison to those with other competing cations suggest that the Fe–FA complexes are relatively stable in a soil environment.
    Type of Medium: Electronic Resource
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