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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 67 (1999), S. 213-218 
    ISSN: 1588-2837
    Keywords: Partial oxidation ; hydrocarbons ; catalyst circulation ; multiplicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A mathematical modeling of a dual-reactor system based on a simple kinetic scheme with two types of sites (accounting for deep and partial oxidation) has been performed. It has been shown that it is possible to regulate the state of a catalyst in the reaction zone by varying the rate of the catalyst circulation between the reactors, thus, significantly increasing the reaction selectivity. A region of multiplicity of the process stationary regimes has been found. This region appeared to become smaller with the increase of the catalyst circulation rate.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 66 (1999), S. 47-54 
    ISSN: 1588-2837
    Keywords: Partial oxidation ; hydrocarbons ; catalyst circulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A simple kinetic model for the partial oxidation of hydrocarbons on two types of sites was used to study the factors influencing the selectivity to the desired product. It is possible to increase the selectivity significantly by regulating the ratio of the surface concentrations of partial and deep oxidation sites by a periodic temperature treatment.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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