ISSN:
1572-8927
Keywords:
Transference numbers
;
concentrated electrolyte
;
hydrochloric acid
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Ion-transfer parameters of aqueous hydrochloric acid over a wide molality range have been re-investigated taking the concurrent solventtransfer into due account. In this context, the transference numbers for the hydrogen ion τH and for water τw have been determined from 10−2 to 15 mol-kg−1, together with the corresponding infinite-dilution values τ H o and τ w o , by processing a set of nearly a hundred emf measurements (some twenty of them new for this work) on HCl concentration cells with transference with both cation-reversible and anion-reversible electrode pairs.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01150871
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