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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 100 (2000), S. 233-242 
    ISSN: 1572-9613
    Schlagwort(e): equations of state ; primitive model ; quantum perturbation theory ; classical perturbation theory ; hydrogen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The restricted primitive model is an electrically neutral, classical model consisting of hard spheres charged either +q or −q. We show that, by appropriately selecting the diameter of the hard spheres, the pressure when q=0 can be made equal to that for a fluid of Maxwell–Boltzmann point ions and an ideal Fermi gas of electrons. We compare the series expansion of these classical and quantum systems and find that, except for intermediate de Broglie density and moderate to strong electrical interaction strength, the restricted primitive model gives a reasonable representation of the pressure of the corresponding quantum system. Much of the current interest, however, has been focused on the above, excepted region.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 835-844 
    ISSN: 1572-9567
    Schlagwort(e): adsorption ; graphite ; hydrogen ; molecular simulation ; path integral
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Molecular simulations of adsorption isotherms for hydrogen on graphite and graphitic slit pores are presented. The simulations employ the path integral isomorphism of Feynman to rigorously account for the quantum nature of the adsorbate. The isosteric heat of adsorption of para-hydrogen on planar graphite is computed from several different solid–fluid potential models and compared with experiment. The adsorption isotherm for hydrogen on the graphite basal plane was computed at 20 K and compared with experiment. Agreement with experiment is very good. Adsorption isotherms for hydrogen in slit pores of two different pore widths are computed at 20 K and compared with results from classical simulations. Quantum and classical isotherms exhibit qualitatively different behavior.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 8 (1966), S. 135-151 
    ISSN: 0006-3592
    Schlagwort(e): Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Foam separation of microorganisms has been investigated with varying success by many workers, usually at high rates of gas flow. Microflotation was developed to overcome some of the disadvantages inherent in these high gas-flow-rate processes and is introduced in this paper as a new technique for the foam separation of microorganisms at low gas-flow rates. With microflotation, a stable surface phase is produced by adding an insoluble collector such as a long-chain fatty acid or amine. The formation of an insoluble surface phase eliminates the need for high foaming. Low rates of gas flow are used resulting in a more efficient separation and a less voluminous and drier surface phase upon which to collect the microorganisms. The efficiency of this technique is also improved by using flotation aids such as frothers and flocculents. Frothers are used to improve the collector properties of the surfactant and to refine further the small bubbles produced by a very fine sparger. Small concentrations of flocculents, such as alum, are used to partially agglomerate the organisms and provide sites for adsorption of collector. The work described in this paper is preliminary in nature, designed to illustrate that a low flow-rate process may be used to separate microorganisms and to stimulate further research. The applications discussed are removal of the bacterium, Escherichia coli, and alum, and two species of algae, Chlamydomonas reinhardtii and Chlorella ellipsoidea, using stearylamine without alum. The frother used was ethanol.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 16 (1974), S. 1227-1243 
    ISSN: 0006-3592
    Schlagwort(e): Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An intracellular, thermostable, neutral α-galactosidase (α-D-galactoside galactohydrolase EC 3.2.1.32) was produced in pilot plant quantities from a strain of Bacillus stearothermophilus. The organism was cultured at 50°C in a soluble neutral medium containing water extract of soybean meal (3%) and 0.5% yeast extract. The enzyme biosynthesis was inducible and sensitive to catabolite repression. After autolysis of the cells, the α-galactosidase was selectively and quantitatively complexed from clarified beer directly onto DEAE Sephadex; and enzyme-rich fractions were batchwise eluted with an increasing gradient of NaCl solutions. The eluates were given two consecutive isopropyl alcohol precipitations, and the aqueous solutions of the second precipitate were dialyzed and lyophilized. Final product activity recovery was 72% based on the crude fermentation beer. Best specific activity was 5.2 u/mg protein. Further laboratory purification (DEAE Sephadex and Bio-Gel P200) yielded a product with 14.2 u/mg protein.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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